Is Silicone Bakeware Really Safe?

The following post is from Katie of Kitchen Stewardship:

source: Mary Amanda Thompson

With holiday baking coming up and gift season to boot, I’ve been thinking again about the safety of silicone bakeware. Silicone pans, baking mats, and cooking utensils are not only a huge trend in the common culture but also touted as a way to “bake green” since you can avoid throwing away aluminum foil or parchment paper if you use and reuse silicone baking mats. They make great gifts since they’re generally both cute and affordable. But is silicone really a safe choice for your health?

I’ve been using the baking mats for years under the pretense that silicone is safe, especially compared to the hazards of aluminum and the many safety issues surrounding Teflon.

It seems that a few times a year, I’m asked to explain my rationale for choosing silicone bakeware, and since I can never remember the answer, it’s time to officially revisit that issue: Is silicone bakeware safe? Can it leach into the food or offgas into the air?

The Composition of Silicone

Silicone is a synthetic (man-made) material created by bonding silicon with oxygen. I think I often type “silicon baking mats” but that’s wrong – silicone is the material in the bakeware. Silicon is right on the periodic table, a natural element that is in sand and makes up 28% of the earth’s crust. However, I don’t eat on the earth’s crust. “Is a natural substance” can’t be the end of one’s material safety research.

Silicone’s Interactions with Food

Silicone is FDA approved as a food-safe substance. (Note: that sentence means very little, since the FDA approves a whole bunch of things for human consumption that I don’t trust, like hydrogenated oils, for example.) Almost all the sources I’ve found state that silicone is inert, doesn’t react with food or liquids, and doesn’t offgas chemical fumes. Those that stated otherwise were usually single people in a forum or comments railing about silicone being toxic.

Sources that claim “inert” and seem very genuine include Dr. Weil, Scientific American, and the research at Green Living Tips. Sources that claim “silicone offgasses” include the husband of one of my own readers, a material science engineer, who “will not touch the stuff.”

However, there haven’t actually been studies testing silicone’s reactions with food under heat. The “nonreactive” claim is just based on the fact that silicon (the element) is “inert.” Again, let’s be serious: just because something in nature is fairly stable doesn’t mean I’ll necessarily cook and eat on it.

Note: there is a discrepancy between food-grade silicone and industrial grade silicone, just something to take note of when doing research on the safety of silicone in general.

Concerns About the Dangers of Silicone in Baking/Cooking

source: scubadive67

With all of that said, here are some things to keep in mind:

  • Lower quality silicone coatings contain filler that may be hazardous. Most sites say that if any white shows through when you twist your silicone bakeware, there are probably fillers. (Going to the kitchen to twist some silicone, excuse me a moment…)
  • The oils in silicone, which are very powerful and toxic, may “migrate” from the material, but I can’t find any real data.
  • Some sources offer concerns about bright colors and leaching.
  • Some (many?) have concerns about odors during use, but that may be related to the fillers, and not the silicone. I do notice an odor or smoking every so often, especially when oil hits the surface (like when roasting pumpkin seeds tossed in EVOO).
  • Many silicone baking mats are actually made of fiberglass covered on both sides with silicone, so unless you want to risk fiberglass in your food, don’t cut on the mats!
  • It’s reasonably new, so long-term studies haven’t been performed on cookware that has been exposed to high temperatures over very long periods.

The Bottom Line on Silicone Bakeware

I take three issues into account when making purchases for the kitchen: Is it safe for my family? Is it safe for the planet? Does it make the act of making food easier or tastier?

Is it safe?

Just because there aren’t many studies done on food safety and silicone that show that it is not safe most certainly doesn’t mean it is safe. All over the Internet, people are basically saying, “I can’t find anything dangerous about silicone, so I assume it’s a safe material.” That’s basically what I’ve said over the years, and now I’ve just contributed another article to the vastness of the Internet that says little to nothing about the safety of silicone. Drat.

The bottom line on safety is:

  • Check your manufacturer for other materials possible contaminating your silicone bakeware.
  • Treat it well – no cutting on those baking mats!
  • If you want to be very conservative, skip the silicone and stick with glass, cast iron, or stainless steel for cooking and baking and unbleached parchment paper if you need something flexible.

Is it good for the environment?

Some sources say silicone can be recycled, which is great. It doesn’t take more energy to create than glass or mining metal for pots and pans, and it is not toxic to aquatic or soil organisms.

So for the earth, silicone bakeware is a fine choice compared to just about anything else out there, and better than Teflon, which contains chemicals that won’t break down at all.

Does it create a happy kitchen experience?

Other than when I get them all stained up, I love my baking mats. They’re awesome for homemade crackers and cookies especially. I also swear by my silicone “spoonula” for scrambling eggs in the pan and other stovetop cooking.

However, many people don’t like the way silicone pans, muffin cups, and loaf pans bake unevenly and don’t properly brown the food. I found the muffin tin to be a beast to clean, much worse than its metal counterpart. I gave mine away after one use and went back to paper liners. The “nonstick” claim leaves a lot to be desired on the three-dimensional products, but the mats are still my friend…unless I decide they might be toxic. Sigh.

Sources: 1, 2, 3, 4, 5, 6

Do you use silicone bakeware? Why or why not?

Katie Kimball has been “green” since 5th grade when she read 50 Things Kids Can Do to Save the Earth. She remains slightly disappointed that she didn’t actually save the whole thing back then, but now that she has 3 kiddos counting on her, she keeps plugging away hopefully. Katie blogs at Kitchen Stewardship about real food and natural living and is the author of Healthy Snacks to Go and other eBooks, available for Kindle.
  • barfoo

    Thanks for an informative, balanced post. I like the idea of silicone, but geez, the smells it gives off when heated, and the way it’s a sponge for food odors make me wonder. Why can’t someone test what gasses actual, store-bought silicone items actually emit?

  • danib

    This is the best discussion on the debate about the safety of silicone. thanks so much!

  • RoMissoula

    I have a silicone coffee pour over funnel; I do use unbleached filters in the funnel; however, I and am wondering if it is truly “safe”.

  • Wilma Laura Wiggins

    Bless your heart Katie for stickin’ to it in your efforts to save the earth. You remind me of my 3 year old granddaughter who would come in from outdoors carrying handsful of trash. I asked her why are you bringing in trash? and she said “I just want to save the world”. She had been out picking up trash in the apartment grounds.

  • Ali

    You should try the Silpat by Demarle. It is food grade silicone that is Kosher certified. No strange smell and very easy to clean. Just soap and hot water.

  • Dianne Smith

    Thanks for this article. Time will tell if the silicone is long-term safe with heat. Sadly. It would be nicer to know now before health damage.occurs. :P
    I have a silicone muffin pan and steamer tray that came with my Microhearth microwave cookware and I still can’t decide if I’m brave enough to use it. I LOVE the pan though and it’s a nicely made product that I have been using for over a year to make everything you could imagine – in a microwave. I have written to the manufacturer to make sure the silicone is 100% with no fillers. I bet it is, since the company seems conscientious about food grade and safety.
    I really want to make muffins in my microwave…
    Is there any info about the safety of silicone cookware used in a microwave?? I’ve been looking and have not found anything as yet and I’m hoping that Microhearth has already eliminated any health concerns before they released their product since they are still in business after so many years (one would think they would have failed by now if their products were unsafe).
    Just another silicone safety question to add to your pile…

    • Sande

      It might be helpful to also research the horrible dangers of using a microwave. Google microwave dangers. I was shocked the first time I saw it. What else besides silicone could I use to strain tea using a wide mouth canning jar funnel? Love all the comments and think I will stay away from silicone.

  • L.

    Just purchased online silicon ice trays. When I open the package it was in, there was a chemical smell. When I put nose to the bottom if the ice tray (where various colors – pink, purple, yellow) of what I believe is the manufacture’s claim to be silicon (so that ice cubes can be popped out). Want to
    Know how safe this is?

    Product is distributed by Meridian Point Products, Somerset, NJ and is made in
    CHINA. UPC is 754814025215.
    Thank you.

  • smurfett

    I read in the Bread Baker’s Apprentice that parchment paper is just coated with Silicone, so what’s the difference then.

  • Susan Gregg

    I have never used silicon bakeware & was just researching it because I wanted to buy a muffiin pan. After reading this, think I’ll jut buy muffin papers instead. Thanks!

  • Mari

    I just can’t bake in silicone–but I do buy nice ones cheap at yard sales (because not many do bake with them and they don’t know what else to use them for) Silicone bakeware is FANTASTIC for freezing and making healthy “candy” with coconut oil. I use the silicone mini bread pans for freezing broth. Tovolo makes a nice twisty silicone popsicle mold. I love the gigantic ice cube trays for freezing leftovers or manageable amounts of beans or veggies to add to soups, leftovers, babyhood, etc. I roast red peppers by cutting off both ends and flattening the rest into a long rectangle. After they are peeled and cooled I roll them up into layers that look like big rosettes. When frozen put in zip freezer bag. Easy to slice when frozen and add to anything.

  • Hilary Wekins

    I remember for a chemistry lab experiment, we used silicone bakeware and exposed them under cake-baking temperatures, then under extreme heat. They are as proclaimed; the food was cooked almost perfectly, with minimal chemical residue (Yes there is residue but at trace amounts).

    This partially discouraged me to use silicon products, so I guess I’ll stick to non-stick metal pans.